Product ID:R495 CLEANER
MSDS Date:08/04/1986
FSC:6850
NIIN:00N082316
MSDS Number: CGCRM

MALLINCKRODT CHEMICAL INC

PARIS, KY 40362
US

Emergency Phone: 314-539-1600; 314-982-5000

Info Phone: 314-539-1600

Cage: 23104

MALLINCKRODT SPECIALTY CHEMICALS CO

PHILLIPSBURG, NJ 08865 US

Telephone: 908-859-2151

Cage: 62910

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM; 450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA 313)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM; 500 STEL

WASH EYES W/PLENTY OF WATER

RTECS: 9999999ZZ

EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION

RTECS: 9999999ZZ

ROOM OR CABINET. SEPARATE FROM OXIDIZING

RTECS: 9999999ZZ

AREAS. DO NOT USE ALUMINUM, MAGNESIUM OR ZINC METAL

RTECS: 9999999ZZ

CONTAINER CLOSED. USE ONLY W/ADEQUATE VENTILATION.

RTECS: 9999999ZZ

SKIN & CLOTHING.

RTECS: 9999999ZZ

A NIOSH APPROVED SUPPLIED AIR FULL FACEPIECE

RTECS: 9999999ZZ

LIMITS. LOCAL EXHAUST VENT IS GENERALLY PREFERRED

RTECS: 9999999ZZ

AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO THE

RTECS: 9999999ZZ

DOCUMENT, "INDUSTRIAL VENTILATION, A MANUAL OF

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (EG,
EPINEPHRINE) MAY BE CONTRA-INDICATED EXC EPT FOR LIFE-SUSTAINING
USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS .
INHAL: MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CAUSE HEADACHE, DIZZINESS, NAUSEA,
FALL IN BLOOD PRESSURE, UNCONSCIOUSNESS & DEATH. MAY CAUSE SENSIT
TO MYOCARDIUM & KIDNEY & LIVER DAMAGE AFTER SEVERE EXPOSURE.
AFFECTS THE CNS. INGEST: SYS TEMIC POISONING MAY OCCUR THRU
INGESTION; SYMPTOMS MAY PARALLEL INHALATION. SKIN CONTACT: MAY
CAUSE MILD (SUPDAT)
Medical Cond Aggravated by Exposure:PRECLUDE PERSONNEL WITH CNS, LIVER
OR HEART DISEASE FROM EXPOSURE. USE OF ALCOHOLIC BEVERAGES MAY
AGGRAVATE SYMPTOMS.

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD.
INGEST: ASPIRATION HAZARD. CALL MD IMMED. IF SWALLOWED GIVE SEVERAL
GLASSES OF MILK OR WATER. IF MED HELP IS NOT IMMED AVAILABLE &
AMOUNT SWALLOWED WAS APPRECIABLE, INDUCE VOMITING. NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERSON. SKIN: REMOVE ANY CONTAMD CLTHG.
WASH (SUPDAT)

Flash Point:118F,48C
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. DO NOT USE
WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE . ABOVE THE FLASH POINT, EXPLOSIVE
VAPOR-AIR MIXTURES MAY BE FORMED.

Spill Release Procedures:DIKE & COVER LEAKING OR SPILLED LIQUID W/DIRT,
VERMICULITE, KITTY LITTER OR OTHER INERT ABSORBENT. COLLECTED WASTE
MAY BE TRANSFERRED TO CLOSED, PREFERABLY METAL CONTAINER & SENT TO
RCRA-APPRVD WASTE DISPOSAL FACILITY. VENTILATE AREA OF LEAK/SPILL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE.
OUTSIDE OR DETACHED STORAGE IS PREFERRED. INSIDE STORAGE SHOULD BE
IN STANDARD FLAMMABLE LIQUIDS STORAGE (ING 5)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:IF THE TLV IS EXCEEDED A NIOSH APPRVD FULL
FACEPIECE CHEMICAL CARTRIDGE RESPIRATOR MAY BE WORN, IN GENERAL, UP
TO 100 TIMES THE TLV OR MAXIMUM USE CONCENTRATION SPECIFIED BY
RESPIRATOR SUPPLIER, WHICH EVER IS LESS. ALTERNATIVELY, (ING 9)
Ventilation:A SYSTEM OF LOCAL &/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURE BELOW THE AIRBORNE EXPOSURE (ING 10)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
WITH THIS MATERIAL.
Supplemental Safety and Health
SOL IN H*2O: PARTIALLY (CA 10%) SOLUBLE IN WATER. EFTS OF OVEREXP:
IRRITATION & REDNESS. EYE CONTACT: LIQUIDS & VAPORS MAY CAUSE
IRRITATION. CHRONIC: PRLNGD/RPTD SKIN CONTACT MAY CAUSE DERMATITIS.
FIR ST AID PROC: SKIN W/SOAP OR MILD DETERGENT & WATER FOR AT LEAST
15 MIN. GET MED ATTN IF IRRITATION DEVELOPS OR (ING 3)

Boiling Pt:B.P. Text:167F,75C
Melt/Freeze Pt:M.P/F.P Text:-31F,-35C
Vapor Pres:100 @ 20C
Vapor Density:4.5
Spec Gravity:1.27
Solubility in Water:SUPDAT
Appearance and Odor:CLEAR, COLORLESS SOLUTION; CHARACTERISTIC ODOR.

Stability Indicator/Materials to Avoid:YES
POWDERED METALS, STRONG ALKALIES.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE.
Hazardous Decomposition Products:OXIDES OF CARBON, HYDROGEN CHLORIDE,
PHOSGENE.

Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.